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1Ylides and imines of phosphorus

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“Ylides and imines of phosphorus” Metadata:

  • Title: ➤  Ylides and imines of phosphorus
  • Author:
  • Language: English
  • Number of Pages: Median: 587
  • Publisher: Wiley
  • Publish Date:
  • Publish Location: New York

“Ylides and imines of phosphorus” Subjects and Themes:

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Access and General Info:

  • First Year Published: 1993
  • Is Full Text Available: Yes
  • Is The Book Public: No
  • Access Status: Printdisabled

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    Ylide

    An ylide (/ˈɪlaɪd/) or ylid (/ˈɪlɪd/) is a neutral dipolar molecule containing a formally negatively charged atom (usually a carbanion) directly attached

    Wittig reaction

    chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide called a Wittig reagent. Wittig reactions are most commonly used to convert

    Nitrile ylide

    Nitrile ylides also known as nitrilium ylides or nitrilium methylides, are generally reactive intermediates formally consisting of a carbanion of an alkyl

    1,3-Dipolar cycloaddition

    dipole or a nucleophilic dipole, which includes azomethine ylide, carbonyl ylide, nitrile ylide, azomethine imine, carbonyl imine and diazoalkane. These

    Azomethine ylide

    Azomethine ylides are nitrogen-based 1,3-dipoles, consisting of an iminium ion next to a carbanion. They are used in 1,3-dipolar cycloaddition reactions

    Johnson–Corey–Chaykovsky reaction

    Corey and Michael Chaykovsky. The reaction involves addition of a sulfur ylide to a ketone, aldehyde, imine, or enone to produce the corresponding 3-membered

    Dicarbon monoxide

    15596-07-3) contains the C2O functionality. Sometimes called Bestmann's Ylide, it is a yellow solid. Frenking, Gernot; Tonner, Ralf "Divalent carbon(0)

    Peterson olefination

    The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α-silyl carbanions (1 in diagram below) with ketones (or aldehydes)

    Zwitterion

    and negatively charged functional groups. (1,2-dipolar compounds, such as ylides, are sometimes excluded from the definition.) Some zwitterions, such as

    Thiamine pyrophosphate

    charges on adjacent atoms is called an ylide, so sometimes the carbanion form of TPP is referred to as the "ylide form". In several reactions, including