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Source: The Open Library
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1A mechanistic study of the reactions of azines and other analogous C=N systems with some oxygen-transfer agents
By Rodrigo Paredes
“A mechanistic study of the reactions of azines and other analogous C=N systems with some oxygen-transfer agents” Metadata:
- Title: ➤ A mechanistic study of the reactions of azines and other analogous C=N systems with some oxygen-transfer agents
- Author: Rodrigo Paredes
- Language: English
- Number of Pages: Median: 65
- Publish Date: 1991
“A mechanistic study of the reactions of azines and other analogous C=N systems with some oxygen-transfer agents” Subjects and Themes:
- Subjects: Organic compounds - Azines - Oxaziridines - Synthesis
Edition Identifiers:
- The Open Library ID: OL25867025M
- Online Computer Library Center (OCLC) ID: 25605215
Access and General Info:
- First Year Published: 1991
- Is Full Text Available: Yes
- Is The Book Public: Yes
- Access Status: Public
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Wiki
Source: Wikipedia
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Oxaziridine
their largest industrial application, oxaziridines are intermediates in the production of hydrazine. Oxaziridine derivatives are also used as specialized
Hydrazine
hydrogen peroxide to the oxaziridine, a three-membered ring containing carbon, oxygen, and nitrogen. Next, the oxaziridine gives the hydrazone by treatment
Davis oxidation
(1992). "Chemistry of oxaziridines. 18. Synthesis and enantioselective oxidations of the [(8,8-dihalocamphoryl)sulfonyl]oxaziridines". The Journal of Organic
Electrophile
the active dioxirane form before proceeding in the catalytic cycle. Oxaziridines such as chiral N-sulfonyloxaziridines effect enantioselective ketone
Davis reagent
Davis reagent (3-phenyl-2-(phenylsulfonyl)-1,2-oxaziridine or 2-(benzenesulfonyl)-3-phenyloxaziridine) is a reagent used for oxidation in the Davis oxidation
Acyloin
deficient oxygen of the oxaziridine ring. This reaction type is extended to asymmetric synthesis by the use of chiral oxaziridines derived from camphor (camphorsulfonyl
Peroxide process
H2O Oxidation of the imine to the oxaziridine: Me(Et)C=NH + H2O2 → Me(Et)CONH + H2O Condensation of the oxaziridine with a second molecule of ammonia
Amination
reactivity may be reversed for some electron-deficient amines, including oxaziridines, hydroxylamines, oximes, and other N–O substrates. When the amine is
Tris(acetylacetonato)iron(III)
polymerization, Fe(acac)3 has been found to catalyze the reaction of N-sulfonyl oxaziridines with olefins to form 1,3-oxazolidine products. GHS: Sigma-Aldrich 517003
Sodium hypochlorite
or sulfones; disulfides or thiols to sulfonyl halides; and imines to oxaziridines. It can also de-aromatize phenols. Heterogeneous reactions of sodium