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Two reasons for remote sensing from the Earth are given: (1) space exploration, particularly below the surfaces or underneath cloud layers, is limited to only a very few planets; and (2) a program of regular monitoring, currently impractical with a limited number of space probes, is required. Reflected solar and nonthermal radiation are discussed. Relativistic electrons, trapped in large magnetospheres on Saturn and Jupiter, are discussed. These electrons produce synchrotron radiation and also interact with the ionosphere to produce bursts of low frequency emission. Because most objects are black-bodies, continuum radiometry is emphasized. Spectroscopic techniques and the measurement of nonthermal emission are also discussed.

The Io sodium cloud model was successfully generated to include the time and spatial dependent lifetime sink produced by electron impact ionization as the plasma torus oscillates about the satellite plane, while simultaneously including the additional time dependence introduced by the action of solar radiation pressure on the cloud. Very preliminary model results are discussed and continuing progress in analysis of the peculiar directional features of the sodium cloud is also reported. Significant progress was made in developing a model for the Io potassium cloud and differences anticipated between the potassium and sodium cloud are described. An effort to understand the hydrogen atmosphere associated with Saturn's rings was initiated and preliminary results of a very and study are summarized.

Remote sensing of planetary atmospheres is not complete without studies of all levels of the atmosphere, including the dense cloudy- and haze filled troposphere, relatively clear and important stratosphere and the upper atmosphere, which are the first levels to experience the effects of solar radiation. High-resolution spectroscopy can provide valuable information on these regions of the atmosphere. Ultra-high spectral resolution studies can directly measure atmospheric winds, composition, temperature and non-thermal phenomena, which describe the physics and chemistry of the atmosphere. Spectroscopy in the middle to long infrared wavelengths can also probe levels where dust of haze limit measurements at shorter wavelength or can provide ambiguous results on atmospheric species abundances or winds. A spectroscopic technique in the middle infrared wavelengths analogous to a radio receiver. infrared heterodyne spectroscopy [1], will be describe and used to illustrate the detailed study of atmospheric phenomena not readily possible with other methods. The heterodyne spectral resolution with resolving power greater than 1,000.000 measures the true line shapes of emission and absorption lines in planetary atmospheres. The information on the region of line formation is contained in the line shapes. The absolute frequency of the lines can be measured to I part in 100 ,000,000 and can be used to accurately measure the Doppler frequency shift of the lines, directly measuring the line-of-sight velocity of the gas to --Im/s precision (winds). The technical and analytical methods developed and used to measure and analyze infrared heterodyne measurements will be described. Examples of studies on Titan, Venus, Mars, Earth, and Jupiter will be presented. 'These include atmospheric dynamics on slowly rotating bodies (Titan [2] and Venus [3] and temperature, composition and chemistry on Mars 141, Venus and Earth. The discovery and studies of unique atmospheric phenomena will also be described, such as non-thermal and lasing phenomena on Mars and Venus, mid-infrared aurora on Jupiter [5], and results of small body impacts on Jupiter [6]. The heterodyne technique can also be applied for detailed study of the Earth's stratosphere and mesosphere by measuring trace constituent abundances and temporal and spatial variability as well as winds, which provide information of transport. All ground-based measurements will be described as complementary and supporting studies for on-going and future space missions [7] (Mars Express, Venus Express, Cassini Huygens, JUNO, ExoMars Trace Gas Orbiter, and the Europa Jupiter System Mission, an Earth Science Venture Class missions), Proposed instrument and technology development for a space flight infrared heterodyne spectrometer will be described.

An inversion method which is applicable to high resolution observations where the spectral lines are fully resolved is described. The technique is based on matching calculated slopes of the spectral line profiles with slopes of the observed lineshapes, and involves finding an inverse solution to the derivative of the radiative transfer equation with respect to frequency. The method is applied to inversion of ozone absorption lines in the earth's atmosphere and the results are compared with those obtained by a conventional method. Advantages include narrower weighting functions providing a higher vertical resolution; higher atmospheric level which may be probed, more faster and more stable convergence, and more accurate retrieved profiles.

Submillimeter remote sensing of planetary and cometary atmospheres have been proposed for Venus and Mars while MIRO on Rosetta will observe the coma of Comet 67P/Churyumov - Cierasimenko in December 2015, UARS and AURA MLS have observed millimeter and submillimeter molecule emissions in the Earth's stratosphere for many decades, Observations of submillimeter wave molecular emissions provide a wealth of information not obtainable by alternative techniques. Submillimeter line emissions exhibit linear temperature dependence, insensitivity to aerosol scattering, extinction, and have separated transitions with well determined line-shapes. These observations have high sensitivities to trace chemical species and can; 1) Fully resolve the line profiles of molecules with high resolution, 2) Provide deterministic retrievals of species abundance, temperature, and pressure, and 3) Measure Doppler shifts of detected molecules for wind velocities.

The tenuous atmospheres and ionospheres of comets and outer planet satellites share many common properties and features. Such similarities include a strong interaction with their outer radiation, fields and particles environs. For comets the interaction is with the magnetized solar wind plasma, whereas for satellites the interaction is with the strongly magnetized and corotating planetary magnetospheric plasma. For this reason there are many common or analogous physical regimes, and many of the same modeling techniques are used to interpret remote sensing and in situ measurements in order to study the important underlying physical phenomena responsible for their appearances. We present here a review of various modeling approaches which are used to elucidate the basic properties and processes shaping the energetics and dynamics of these systems which are similar in many respects.

The analysis of super-circular entry is developed around a new dimensionless parameter which combines certain conditions at the conic perigee altitude with certain characteristics of the vehicle; this parameter conveniently determines either deceleration-limited or heating limited corridor widths for elliptic, parabolic, or hyperbolic approach trajectories. Illustrative calculations of corridor widths and the associated guidance problems are presented for Venus, Earth, Mars, Jupiter, and Titan. Generalized curves are presented for application to various entry conditions.

Scientists utilize radio links between spacecraft and Earth or between spacecraft to examine changes in the phase/frequency and amplitude of radio signals to investigate atmospheres and ionospheres rings surfaces shapes gravitational fields and dynamics of solar system bodies.

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments and earth-based radio astronomical observations can be used to infer abundances of microwave absorbing atmospheric constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically derived microwave absorption properties for such atmospheric constituents, or using laboratory measurements of such properties under environmental conditions which are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. The recognition of the need to make such laboratory measurements of simulated planetary atmospheres over a range of temperatures and pressures which correspond to the altitudes probed by both radio occultation experiments and radio astronomical observations, and over a range of frequencies which correspond to those used in both radio occultation experiments and radio astronomical observations, has led to the development of a facility at Georgia Tech which is capable of making such measurements. The goal of this investigation was to conduct such measurements and to apply the results to a wide range of planetary observations, both spacecraft and earth-based, in order to determine the identity and abundance profiles of constituents in those planetary atmospheres.

Measurements of the temperature dependence between 77 and 333 K of the infrared spectrum of cyclic octatomic sulfur are reported. It is suggested that the 23 micrometer Jovian feature is not due to 3 sub 8 and that the temperature dependence of the frequency of the 835/cm band of S sub 8 may be a useful temperature marker in planetary studies.

After long arduous work with the simulator, measurements of the refractivity and absorptivity of nitrogen under conditions similar to those for Titan were completed. The most significant measurements, however, were those of the microwave absorption from gaseous ammonia under simulated conditions for the Jovian atmospheres over wavelengths from 1.3 to 22 cm. The results of these measurements are critical in that they confirm the theoretical calculation of the ammonia opacity using the Ben-Reuven lineshape. The application of both these results, and results obtained previously, to planetary observations at microwave frequencies were especially rewarding. Applications of the results for ammonia to radio astronomical observations of Jupiter in the 1.3 to 20 cm wavelength range and the application of results for gaseous H2SO4 under simulated Venus conditions are discussed.

Initial work was concerned with determining whether the radiation emitted from a laser source could be sufficiently collimated to provide a suitable source for a nephelometer-type instrument. It was necessary to develop a standard scatterer that could be used to evaluate the performance of a nephelometer. The possible use of a gallium arsenide diode as a radiation source also was investigated. The first of these utilized a single lens to focus the light scattered from a target onto a ring detector. The second configuration used reflecting and refracting axicons as optical-system elements. The work performed in each of these areas is described.

Numerical experiments are performed to examine the effects of line shape and band structure on the radiative equilibrium temperature profile in planetary atmospheres. In order to accurately determine these effects, a method for calculating radiative terms is developed which avoids the usual approximations. It differs from the more commonly used methods in that it allows arbitrary dependence of the absorption coefficient on wave number, without requiring tedious line by line integration and without the constraints of band models. The present formulation is restricted to homogeneous atmospheres but the concept can be extended to the more general case. The numerical experiments reveal that the line shape and band structure of the absorbing gases have a large effect on temperatures in the higher layers of the atmosphere (corresponding to the stratosphere and mesosphere). The more nongrey the spectrum (that is, the higher the peaks and the deeper the troughs in the spectrum), the lower the temperature.

A free convection parameterization has been introduced into the Mars Planetary Boundary Layer Model (MPBL). Previously, the model would fail to generate turbulence under conditions of zero wind shear, even when statically unstable. This in turn resulted in erroneous results at the equator, for example, when the lack of Coriolis forcing allowed zero wind conditions. The underlying cause of these failures was the level 2 second-order turbulence closure scheme which derived diffusivities as algebraic functions of the Richardson number (the ratio of static stability to wind shear). In the previous formulation, the diffusivities were scaled by the wind shear--a convenient parameter since it is non-negative. This was the drawback that all diffusivities are zero under conditions of zero shear (viz., the free convection case). The new scheme tests for the condition of zero shear in conjunction with static instability and recalculates the diffusivities using a static stability scaling. The results for a simulation of the equatorial boundary layer at autumnal equinox are presented. (Note that after some wind shear is generated, the model reverts to the traditional diffusivity calculation.)

We present new self-consistent atmosphere models for transiting planets TrES-1 and HD209458b. The planets were recently observed with the Spitzer Space Telescope in bands centered on 4.5 and 8.0 $\mu$m, for TrES-1, and 24 $\mu$m, for HD209458b. We find that standard solar metallicity models fit the observations for HD209458b. For TrES-1, which has an T_eff ~300 K cooler, we find that models with a metallicity 3-5 times enhanced over solar abundances can match the 1$\sigma$ error bar at 4.5 $\mu$m and 2$\sigma$ at 8.0$\mu$m. Models with solar abundances that included energy deposition into the stratosphere give fluxes that fall within the 2$\sigma$ error bars in both bands. The best-fit models for both planets assume that reradiation of absorbed stellar flux occurs over the entire planet. For all models of both planets we predict planet/star flux ratios in other Spitzer bandpasses.

A unified overview is presented for chemical kinetics and chemical modeling in planetary atmospheres. The recent major advances in the understanding of the chemistry of the terrestrial atmosphere make the study of planets more interesting and relevant. A deeper understanding suggests that the important chemical cycles have a universal character that connects the different planets and ultimately link together the origin and evolution of the solar system. The completeness (or incompleteness) of the data base for chemical kinetics in planetary atmospheres will always be judged by comparison with that for the terrestrial atmosphere. In the latter case, the chemistry of H, O, N, and Cl species is well understood. S chemistry is poorly understood. In the atmospheres of Jovian planets and Titan, the C-H chemistry of simple species (containing 2 or less C atoms) is fairly well understood. The chemistry of higher hydrocarbons and the C-N, P-N chemistry is much less understood. In the atmosphere of Venus, the dominant chemistry is that of chlorine and sulfur, and very little is known about C1-S coupled chemistry. A new frontier for chemical kinetics both in the Earth and planetary atmospheres is the study of heterogeneous reactions. The formation of the ozone hole on Earth, the ubiquitous photochemical haze on Venus and in the Jovian planets and Titan all testify to the importance of heterogeneous reactions. It remains a challenge to connect the gas phase chemistry to the production of aerosols.

Radio absorptivity data for the Venus middle atmosphere (1 to 6 atm, temperatures from 500 to 575K) obtained from spacecraft radio occultation experiments (at 3.6 to 13.4 cm wavelengths) and earth-based radio astronomical observations (1 to 3 cm wavelength range) are compared to laboratory observations at the latter wavelength range under simulated Venus conditions to infer abundances of microwave-absorbing atmospheric constituents, i.e. H2SO4 in a CO2 atmosphere.

Progress is reported in modeling cometary emission in the 18-cm OH transition with specific application and predictions for Comet Halley. Radiative transfer is also being studied in rough and porous media. The kinematics of the cold, dark interstellar cloud Li34N were examined, and CO monitoring of Venus and Mars continues. Analysis of 3.4 mm maps of the lunar surface shows thermal anomalies associated with such surface features as the Crater Copernicus, Mare Imbrium, Mare Nubium, Mare Serenitatis, and Mare Tranquillatis.

The long propagation paths involved in radio and stellar occultations by turbulent planetary atmospheres require that the classical, weak scattering scintillation theory be expanded to account for the inhomogeneous ambient atmosphere upon which the turbulence is superimposed. Such coupling between the turbulent and the ambient components of refractivity reduces the scintillation index by less than a factor of two in shallow radio occultations. For stellar occultations the reduction varies between this value for very small projected stellar radii, to approximately a factor of 3.6 when the projected stellar radius above the planetary limb greatly exceeds the radius of the free-space Fresnel zone at this distance. More profound changes are found in the scintillation power spectrum, the shape of which depends strongly on both occultation depth and geometry when coupling to the inhomogeneous background is properly accounted for. Second-order, systematic propagation effects calculated from both geometrical optics and a wave-optical formulation show that the average phase velocity is increased in the presence of turbulence. The finite wavelength dependence of the phase path bias implies that an initially non-dispersive medium becomes slightly dispersive by the addition of turbulence. Atmospheric profiles derived from occultations by turbulent planetary atmospheres differ only slightly from those of the corresponding non-turbulent atmosphere when the weak scattering condition is satisfied.

Results show that Amalthea is likely to form a tightly-bound partial toroidal-shaped hydrogen cloud about its planet, while Ganymede, Callisto and Titan may have rather large, complete and nearly symmetric toroidal-shaped clouds. The toroidal cloud for Amalthea compares favorably with spacecraft data of Pioneer 10 for a satellite escape flux of order 10 to the 11th power atoms/sq cm/sec. Model results for Ganymede, Callisto and Titan suggest that these extended hydrogen atmospheres are likely to be detected by the Voyager spacecrafts and that Titan's cloud might also be detected by the Pioneer 11 spacecraft. Ions created because of atoms lost through ionization processes from these four extended hydrogen atmospheres and from the sodium cloud of Io are discussed.

We introduce an innovative concept for inferring altitude profiles of horizontal wind in planetary atmospheres by measuring the Doppler shift of multiple emission lines versus altitude. Instruments using this approach will be especially well suited for interplanetary missions because they will be compact, rugged, and lightweight while minimizing power consumption and maximizing sensitivity, all without moving parts.

Model calculations for the brightness of the sodium cloud in Region A were performed to clarify the role played by the plasma torus sink in producing the east-west intensity asymmetry observed in the sodium D-lines. It was determined that the east-west electric field, proposed by Barbosa and Kievelson (1983) and Ip and Goertz (1983) to explain the dawn-dusk asymmetry in the torus ion emissions measured by the Voyager UVS instrument, could also produce the east-west sodium intensity asymmetry discovered earlier by Bergstralh et al. (1975, 1977). Model results for the directional features of the sodium cloud are also reported. The completion of the development of the Io potassium cloud model, progress in improving the Titan hydrogen torus model, and efforts in developing our model for hydrogen cometary atmospheres are also discussed.

Topics covered include: the broadening of individual lines in the CO fundamental by various gases; total band absorptance as a function of absorber thickness and total effect pressure at various temperatures for bands of CO and N2O; nitric acid vapor content in the region of the ozone layer; optical properties of solid NH3; HSO4 concentration in Venus clouds; Burch's law of multiplicative transmittance for mixing absorbing gases when their lines are broadened by helium and hydrogen; ling strength and self-broadening parameters in the v3 fundamental of CO2 and N2O; optical constants of liquid ammonia, liquid methane, saturated hydrocarbons, ammonium hydride and ammonium salts.

Equilibrium temperature distribution, thermal emission, and limb function computed for Venus cloud cover model

Radiative equilibrium in planetary atmospheres - application of strong line absorption law to atmosphere of venus

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments and Earth-based radio astronomical observations can be used to infer abundances of microwave absorbing atmospheric constituents in those atmospheres, as long as reliable information regarding the microwave absorping properties of potential constituents is available. The use of theoretically derived microwave absorption properties for such atmospheric constituents, or laboratory measurements of such properties under environmental conditions which are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. Laboratory measurement of the microwave properties of atmospheric gases under simulated conditions for the outer planets were conducted. Results of these measurements are discussed.

The Fourier-transform Fabry-Perot pulsed-molecular-beam microwave spectrometer at NIST was used to study the microwave spectra of a number of molecular dimers and trimers that may be present in planetary atmospheres. The weak van der Waals bonds associated with these species usually give rise to rotational-tunneling splittings in the microwave spectra. The microwave spectrum of the water dimer species was used to illustrate the complications that can arise in the study of the rotational spectra of these loosely bound species. In addition to the water dimer species, the microwave spectra of the following hydrogen-bonded and van der Waals complexes were studied: (CO2)2-H2O, CO2-(H2O)2, CO2-H2S, N2-H2O, CO-H2O, SO2-H2O, and O3-H2O.

Scientific missions to comets, near earth space, and planetary atmospheres require particulate and mass accumulation instrumentation for both scientific and navigation purposes. The Rupprecht & Patashnick tapered element oscillating microbalance can accurately measure both mass flux and mass distribution of particulates over a wide range of particle sizes and loadings. Individual particles of milligram size down to a few picograms can be resolved and counted, and the accumulation of smaller particles or molecular deposition can be accurately measured using the sensors perfected and toughened under this contract. No other sensor has the dynamic range or sensitivity attained by these picogram direct mass measurement sensors. The purpose of this contract was to develop and implement reliable and repeatable manufacturing methods; build and test prototype sensors; and outline a quality control program. A dust 'thrower' was to be designed and built, and used to verify performance. Characterization and improvement of the optical motion detection system and drive feedback circuitry was to be undertaken, with emphasis on reliability, low noise, and low power consumption. All the goals of the contract were met or exceeded. An automated glass puller was built and used to make repeatable tapered elements. Materials and assembly methods were standardized, and controllers and calibrated fixtures were developed and used in all phases of preparing, coating and assembling the sensors. Quality control and reliability resulted from the use of calibrated manufacturing equipment with measurable working parameters. Thermal and vibration testing of completed prototypes showed low temperature sensitivity and high vibration tolerance. An electrostatic dust thrower was used in vacuum to throw particles from 2 x 10(exp 6) g to 7 x 10(exp -12) g in size. Using long averaging times, particles as small as 0.7 to 4 x 10(exp 11) g were weighted to resolutions in the 5 to 9 x 10(exp -13) g range. The drive circuit and optics systems were developed beyond what was anticipated in the contract, and are now virtually flight prototypes. There is already commercial interest in the developed capability of measuring picogram mass losses and gains. One area is contamination and outgassing research, both measuring picogram losses from samples and collecting products of outgassing.

A summary final report of work accomplished is presented. Work was performed in the following areas: (1) Galileo Probe science analysis, (2) Galileo probe Atmosphere Structure Instrument, (3) Mars Pathfinder Atmosphere Structure/Meteorology instrument, (4) Mars Pathfinder data analysis, (5) Science Definition for future Mars missions, (6) Viking Lander data analysis, (7) winds in Mars atmosphere Venus atmospheric dynamics, (8) Pioneer Venus Probe data analysis, (9) Pioneer Venus anomaly analysis, (10) Discovery Venus Probe Titan probe instrument design, and (11) laboratory studies of Titan probe impact phenomena. The work has resulted in more than 10 articles published in archive journals, 2 encyclopedia articles, and many working papers. This final report is organized around the four planets on which there was activity, Jupiter, Mars, Venus, and Titan, with a closing section on Miscellaneous Activities. A major objective was to complete the fabrication, test, and evaluation of the atmosphere structure experiment on the Galileo probe, and to receive, analyze and interpret data received from the spacecraft. The instrument was launched on April 14, 1989. Calibration data were taken for all experiment sensors. The data were analyzed, fitted with algorithms, and summarized in a calibration report for use in analyzing and interpreting data returned from Jupiter's atmosphere. The sensors included were the primary science pressure, temperature and acceleration sensors, and the supporting engineering temperature sensors. Computer programs were written to decode the Experiment Data Record and convert the digital numbers to physical quantities, i.e., temperatures, pressures, and accelerations. The project office agreed to obtain telemetry of checkout data from the probe. Work to extend programs written for use on the Pioneer Venus project included: (1) massive heat shield ablation leading to important mass loss during entry; and (2) rapid planet rotation, which introduced terms of motion not needed on Venus. When the Galileo Probe encountered Jupiter, analysis and interpretation of data commenced. The early contributions of the experiment were to define (1) the basic structure of the deep atmosphere, (2) the stability of the atmosphere, (3) the upper atmospheric profiles of density, pressure, and temperature. The next major task in the Galileo Probe project was to refine, verify and extend the analysis of the data. It was the verified, and corrected data, which indicated a dry abiabatic atmosphere within measurement accuracy. Temperature in the thermosphere was measured at 900 K. Participation in the Mars atmospheric research included: (1) work as a team member of the Mars Atmosphere Working Group, (2) contribution to the Mars Exobiology Instrument workshop, (3) asssistance in planning the Mars global network and (4) assitance in planning the Soviet-French Mars mission in 1994. This included a return to the Viking Lander parachute data to refine and improve the definition of winds between 1.5 and 4 kilometer altitude at the two entry sites. The variability of the structure of Mars atmosphere was addressed, which is known to vary with season, latitude, hemisphere and dust loading of the atmosphere. This led to work on the Pathfinder project. The probe had a deployable meteorology mast that had three temperature sensors, and a wind sensor at the tip of the mast. Work on the Titan atmospheric probe was also accomplished. This included developing an experiment proposal to the European Space Agency (ESA), which was not selected. However, as an advisor in the design and preparation of the selected experiment the researcher interacted with scientist on the Huygens Probe Atmosphere Structure Experiment. The researcher also participated in the planning for the Venus Chemical Probe. The science objectives of the probe were to resolve unanswered questions concerning the minor species chemistry of Venus' atmosphere that control cloud formation, greenhouse effectiveness, and the thermal structure. The researcher also reviewed problems with the Pioneer Venus Probe, that caused anomalies which occurred on the Probes at and below 12.5 km level of the Venus' atmosphere. He convened and participated in a workshop that concluded the most likely hardware cause was insulation failure in the electrical harness outside the Probes' pressure vessels. It was discovered that the shrink tubing material failed at 600K. This failure could explain the anomalies experienced by the probes. The descent data of the Pioneer probes, and the Soviet Vega Lander was analyzed to evaluate the presence of small scale gravity waves in and below the Venus cloud layer.

The research accomplished during this period is briefly summarized. The interior radiances within an optically deep absorbing medium scattering according to the Haze L phase function is discussed along with a method for calculating the radiance and color of the twilight sky. The application of the matrix operator method to calculations of radiance, polarization, and ellipticity of the radiation scattered from homogeneous layers scattering is reported. Reports, and publications are listed.

Extensive Earth-based photography of Mars, Jupiter, and Venus is presented which monitors the atmospheric and/or surface changes that take place day to day. Color pictures are included of the 1973 dust storm on Mars, showing the daily cycle of the storm's regeneration. Martian topography, and the progress of the storm is examined. Areas most affected by the storm are summarized.

Laboratory measurements were conducted to evaluate properties of atmospheric gases under simulated conditions for the outer planets. A significant addition to this effort was the capability to make such measurements at millimeter wavelengths. Measurements should soon be completed on the millimeter wave absorption from ammonia under Jovian conditions. Also studied will be the feasibility of measuring the microwave and millimeter wave properties of phosphine (PH3) under simulated Jovian conditions. Further analysis and application of the laboratory results to microwave and millimeter wave absorption data for the outer planet, such as Voyager Radio Occultation experiments, will be pursued.

Limb darkening of planetary atmospheres in thermal infrared

The development of new types of detectors for analysis of planetary atmospheres is discussed. Initially, the interest was in detectors for use under partial vacuum conditions. The program has been extended to include detectors for use at one atmosphere and adsorption system for control and separation of gases. Results to date have included detectors for O2 and H2 under partial vacuum conditions. Experiments on detectors for use at high pressures began in 1966, and systems for CO, H2, and O2, were reported. Electrically controlled adsorbent was developed. It was demonstrated that under proper conditions a thin film of semiconductor material could be electrically cycled to adsorb and desorb a specific gas. This work was extended to obtain quantitative data on the use of semiconductors as controllable adsorbents.

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments, entry probe radio signal absorption measurements, and earth-based or spacecraft-based radio astronomical (emission) observations can be used to infer abundances of microwave absorbing constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically-derived microwave absorption properties for such atmospheric constituents, or the use of laboratory measurements of such properties taken under environmental conditions that are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. Laboratory measurements have shown that the centimeter-wavelength opacity from gaseous phosphine (PH3) under simulated conditions for the outer planets far exceeds that predicted from theory over a wide range of temperatures and pressures. This fundamentally changed the resulting interpretation of Voyager radio occultation data at Saturn and Neptune. It also directly impacts planning and scientific goals for study of Saturn's atmosphere with the Cassini Radio Science Experiment and the Rossini RADAR instrument. The recognition of the need to make such laboratory measurements of simulated planetary atmospheres over a range of temperatures and pressures which correspond to the altitudes probed by both radio occultation experiments and radio astronomical observations, and over a range of frequencies which correspond to those used in both spacecraft entry probe and orbiter (or flyby) radio occultation experiments and radio astronomical observations, has led to the development of a facility at Georgia Tech which is capable of making such measurements. It has been the goal of this investigation to conduct such measurements and to apply the results to a wide range of planetary observations, both spacecraft- and earth-based, in order to determine the identity and abundance profiles of constituents in those planetary atmospheres,

Part I lists the title and abstract of six papers which resulted from this contract. Part II presents absorption and photoionization coefficients of NH3 in the region 580-1650 A obtained with improved resolution. Both the Hopfield helium continuum and H2 emission sources were used. An ionization potential of 10.166 eV is proposed on the basis of Rydberg band analysis. Part III presents both coefficients of CO2 over the region 580-1670 A determined by the same methods. Photoionization efficiencies range from 60 to 95 per cent, and most bands below 900 A are preionized. The doublet ionization potential (13.786 and 13.766 eV) is confirmed. Part IV presents k and k sub i values of NO in the region 580-1100 A. Most bands are both preionized and predissociated. An absorption curve of H2, ionization potential of COS and scattering of vacuum UV radiation are briefly described in Part V.

The long propagation paths involved in radio and stellar occultations by turbulent planetary atmospheres require that the classical, weak scattering scintillation theory be expanded to account for the inhomogeneous ambient atmosphere upon which the turbulence is superimposed. Such coupling between the turbulent and the ambient components of refractivity reduces the scintillation index by less than a factor of two in shallow radio occultations. For stellar occultations the reduction varies between this value for very small projected stellar radii, to approximately a factor of 3.6 when the projected stellar radius above the planetary limb greatly exceeds the radius of the free-space Fresnel zone at this distance. More profound changes are found in the scintillation power spectrum, the shape of which depends strongly on both occultation depth and geometry when coupling to the inhomogeneous background is properly accounted for. Second-order, systematic propagation effects calculated from both geometrical optics and a wave-optical formulation show that the average phase velocity is increased in the presence of turbulence. The finite wavelength dependence of the phase path bias implies that an initially non-dispersive medium becomes slightly dispersive by the addition of turbulence. Atmospheric profiles derived from occultations by turbulent planetary atmospheres differ only slightly from those of the corresponding non-turbulent atmosphere when the weak scattering condition is satisfied.

We have designed and developed, from scratch, a global circulation model named THOR that solves the three-dimensional non-hydrostatic Euler equations. Our general approach lifts the commonly used assumptions of a shallow atmosphere and hydrostatic equilibrium. We solve the "pole problem" (where converging meridians on a sphere lead to increasingly smaller time steps near the poles) by implementing an icosahedral grid. Irregularities in the grid, which lead to grid imprinting, are smoothed using the "spring dynamics" technique. We validate our implementation of spring dynamics by examining calculations of the divergence and gradient of test functions. To prevent the computational time step from being bottlenecked by having to resolve sound waves, we implement a split-explicit method together with a horizontally explicit and vertically implicit integration. We validate our global circulation model by reproducing the Earth and also the hot Jupiter-like benchmark tests. THOR was designed to run on Graphics Processing Units (GPUs), which allows for physics modules (radiative transfer, clouds, chemistry) to be added in the future, and is part of the open-source Exoclimes Simulation Platform (ESP; www.exoclime.org).

The goal of this research grant was to calculate accurate oscillator strengths and electron collisional excitation strengths for inelastic transitions in atomic species of relevance to Planetary Atmospheres. Large scale configuration-interaction atomic structure calculations have been performed to obtain oscillator strengths and transition probabilities for transitions among the fine-structure levels and R-matrix method has been used in the calculations of electron-ion collision cross sections of C II, S I, S II, S III, and Ar II. A number of strong features due to ions of sulfur have been detected in the spectra of Jupiter satellite Io. The electron excitation cross sections for the C II and S II transitions are studied in collaboration with the experimental atomic physics group at the Jet Propulsion Laboratory. There is excellent agreement between experiment and theory which provide an accurate and broad-base test of the ability of theoretical methods used in the calculation of atomic processes. Specifically, research problems have been investigated for: electron impact excitation cross sections of C II: electron impact excitation cross sections of S III; energy levels and oscillator strengths for transitions in S III; collision strengths for electron collisional excitation of S II; electron impact excitation of inelastic transitions in Ar II; oscillator strengths of fine-structure transitions in neutral sulfur; cross sections for inelastic scattering of electrons from atomic nitrogen; and excitation of atomic ions by electron impact.

This research program addresses two cases of tenuous planetary atmospheres: comets and Io. The comet atmospheric research seeks to analyze a set of spatial profiles of CN in comet Halley taken in a 7.4-day period in April 1986; to apply a new dust coma model to various observations; and to analyze observations of the inner hydrogen coma, which can be optically thick to the resonance scattering of Lyman-alpha radiation, with the newly developed approach that combines a spherical radiative transfer model with our Monte Carlo H coma model. The Io research seeks to understand the atmospheric escape from Io with a hybrid-kinetic model for neutral gases and plasma given methods and algorithms developed for the study of neutral gas cometary atmospheres and the earth's polar wind and plasmasphere. Progress is reported on cometary Hydrogen Lyman-alpha studies; time-series analysis of cometary spatial profiles; model analysis of the dust comae of comets; and a global kinetic atmospheric model of Io.

"Equatorial Currents in Star and Planetary Atmospheres" is an article from Science, Volume 7 . View more articles from Science . View this article on JSTOR . View this article's JSTOR metadata . You may also retrieve all of this items metadata in JSON at the following URL: https://archive.org/metadata/jstor-1760088

The overall goal is to illuminate the mechanisms that control weather and climate on the Earth and other planets. Each planet presents its own puzzling behavior - the stability of jets and vortices in Jupiter's otherwise turbulent atmosphere, the superrotation of the Venus atmosphere, the interplay of dust, polar volatiles, and climate change in Mars, the supersonic meteorology of Io, and the counterintuitive equator-to-pole temperature gradients on the outer planets. The data sets are generally those obtained from spacecraft - cloud-tracked winds, radiometrically inferred temperatures, and the results of in situ observations where appropriate. The approach includes both data analysis and modeling, ranging from analytic modeling to time-dependent numerical modeling of atmospheric dynamics. The latter approach involves the use of supercomputers such as the San Diego Cray. Progress is generally made when a model with a small number of free parameters either fits a data set that has a large number of independent observations or applies to several planets at once.

The early evolution of Earth's atmosphere and the origin of life took place at a time when physical conditions at the Earth where radically different from its present state. The radiative input from the Sun was much enhanced in the high-energy spectral domain, and in order to model early planetary atmospheres in detail, a knowledge of the solar radiative input is needed. We present an investigation of the atmospheric parameters, state of evolution and high-energy fluxes of the nearby star kap^1 Cet, previously thought to have properties resembling those of the early Sun. Atmospheric parameters were derived from the excitation/ionization equilibrium of Fe I and Fe II, profile fitting of Halpha and the spectral energy distribution. The UV irradiance was derived from FUSE and HST data, and the absolute chromospheric flux from the Halpha line core. From careful spectral analysis and the comparison of different methods we propose for kap^1 Cet the following atmospheric parameters: Teff = 5665+/-30 K (Halpha profile and energy distribution), log g = 4.49+/-0.05 dex (evolutionary and spectroscopic) and [Fe/H] = +0.10+/-0.05 dex (Fe II lines). The UV radiative properties of kap^1 Cet indicate that its flux is some 35% lower than the current Sun's between 210 and 300 nm, it matches the Sun's at 170 nm and increases to at least 2-7 times higher than the Sun's between 110 and 140 nm. The use of several indicators ascribes an age to kap^1 Cet in the interval ~0.4-0.8 Gyr and the analysis of the theoretical HR diagram suggests a mass ~1.04 Msun. This star is thus a very close analog of the Sun when life arose on Earth and Mars is thought to have lost its surface bodies of liquid water. Photochemical models indicate that the enhanced UV emission leads to a significant increase in photodissociation rates compared with those commonly assumed of the early Earth. Our results show that reliable calculations of the chemical composition of early planetary atmospheres need to account for the stronger solar photodissociating UV irradiation.

The early evolution of Earth's atmosphere and the origin of life took place at a time when physical conditions at the Earth where radically different from its present state. The radiative input from the Sun was much enhanced in the high-energy spectral domain, and in order to model early planetary atmospheres in detail, a knowledge of the solar radiative input is needed. We present an investigation of the atmospheric parameters, state of evolution and high-energy fluxes of the nearby star kap^1 Cet, previously thought to have properties resembling those of the early Sun. Atmospheric parameters were derived from the excitation/ionization equilibrium of Fe I and Fe II, profile fitting of Halpha and the spectral energy distribution. The UV irradiance was derived from FUSE and HST data, and the absolute chromospheric flux from the Halpha line core. From careful spectral analysis and the comparison of different methods we propose for kap^1 Cet the following atmospheric parameters: Teff = 5665+/-30 K (Halpha profile and energy distribution), log g = 4.49+/-0.05 dex (evolutionary and spectroscopic) and [Fe/H] = +0.10+/-0.05 dex (Fe II lines). The UV radiative properties of kap^1 Cet indicate that its flux is some 35% lower than the current Sun's between 210 and 300 nm, it matches the Sun's at 170 nm and increases to at least 2-7 times higher than the Sun's between 110 and 140 nm. The use of several indicators ascribes an age to kap^1 Cet in the interval ~0.4-0.8 Gyr and the analysis of the theoretical HR diagram suggests a mass ~1.04 Msun. This star is thus a very close analog of the Sun when life arose on Earth and Mars is thought to have lost its surface bodies of liquid water. Photochemical models indicate that the enhanced UV emission leads to a significant increase in photodissociation rates compared with those commonly assumed of the early Earth. Our results show that reliable calculations of the chemical composition of early planetary atmospheres need to account for the stronger solar photodissociating UV irradiation.

The early evolution of Earth's atmosphere and the origin of life took place at a time when physical conditions at the Earth where radically different from its present state. The radiative input from the Sun was much enhanced in the high-energy spectral domain, and in order to model early planetary atmospheres in detail, a knowledge of the solar radiative input is needed. We present an investigation of the atmospheric parameters, state of evolution and high-energy fluxes of the nearby star kap^1 Cet, previously thought to have properties resembling those of the early Sun. Atmospheric parameters were derived from the excitation/ionization equilibrium of Fe I and Fe II, profile fitting of Halpha and the spectral energy distribution. The UV irradiance was derived from FUSE and HST data, and the absolute chromospheric flux from the Halpha line core. From careful spectral analysis and the comparison of different methods we propose for kap^1 Cet the following atmospheric parameters: Teff = 5665+/-30 K (Halpha profile and energy distribution), log g = 4.49+/-0.05 dex (evolutionary and spectroscopic) and [Fe/H] = +0.10+/-0.05 dex (Fe II lines). The UV radiative properties of kap^1 Cet indicate that its flux is some 35% lower than the current Sun's between 210 and 300 nm, it matches the Sun's at 170 nm and increases to at least 2-7 times higher than the Sun's between 110 and 140 nm. The use of several indicators ascribes an age to kap^1 Cet in the interval ~0.4-0.8 Gyr and the analysis of the theoretical HR diagram suggests a mass ~1.04 Msun. This star is thus a very close analog of the Sun when life arose on Earth and Mars is thought to have lost its surface bodies of liquid water. Photochemical models indicate that the enhanced UV emission leads to a significant increase in photodissociation rates compared with those commonly assumed of the early Earth. Our results show that reliable calculations of the chemical composition of early planetary atmospheres need to account for the stronger solar photodissociating UV irradiation.

The objective of this paper is to review the anticipated imaging and remote-sensing technology requirements for aerial vehicle survey missions to other planetary bodies in our Solar system that can support in-atmosphere flight. In the not too distant future such planetary aerial vehicle (a.k.a. aerial explorers) exploration missions will become feasible. Imaging and remote-sensing observations will be a key objective for these missions. Accordingly, it is imperative that optimal solutions in terms of imaging acquisition and real-time autonomous analysis of image data sets be developed for such vehicles.

The long propagation paths involved in radio and stellar occultations by turbulent planetary atmospheres require that the classical, weak scattering scintillation theory be expanded to account for the inhomogeneous ambient atmosphere upon which the turbulence is superimposed. Such coupling between the turbulent and the ambient components of refractivity reduces the scintillation index by less than a factor of two in shallow radio occultations. For stellar occultations the reduction varies between this value for very small projected stellar radii, to approximately a factor of 3.6 when the projected stellar radius above the planetary limb greatly exceeds the radius of the free-space Fresnel zone at this distance. More profound changes are found in the scintillation power spectrum, the shape of which depends strongly on both occultation depth and geometry when coupling to the inhomogeneous background is properly accounted for. Second-order, systematic propagation effects calculated from both geometrical optics and a wave-optical formulation show that the average phase velocity is increased in the presence of turbulence. The finite wavelength dependence of the phase path bias implies that an initially non-dispersive medium becomes slightly dispersive by the addition of turbulence. Atmospheric profiles derived from occultations by turbulent planetary atmospheres differ only slightly from those of the corresponding non-turbulent atmosphere when the weak scattering condition is satisfied.

The long propagation paths involved in radio and stellar occultations by turbulent planetary atmospheres require that the classical, weak scattering scintillation theory be expanded to account for the inhomogeneous ambient atmosphere upon which the turbulence is superimposed. Such coupling between the turbulent and the ambient components of refractivity reduces the scintillation index by less than a factor of two in shallow radio occultations. For stellar occultations the reduction varies between this value for very small projected stellar radii, to approximately a factor of 3.6 when the projected stellar radius above the planetary limb greatly exceeds the radius of the free-space Fresnel zone at this distance. More profound changes are found in the scintillation power spectrum, the shape of which depends strongly on both occultation depth and geometry when coupling to the inhomogeneous background is properly accounted for. Second-order, systematic propagation effects calculated from both geometrical optics and a wave-optical formulation show that the average phase velocity is increased in the presence of turbulence. The finite wavelength dependence of the phase path bias implies that an initially non-dispersive medium becomes slightly dispersive by the addition of turbulence. Atmospheric profiles derived from occultations by turbulent planetary atmospheres differ only slightly from those of the corresponding non-turbulent atmosphere when the weak scattering condition is satisfied.

The long propagation paths involved in radio and stellar occultations by turbulent planetary atmospheres require that the classical, weak scattering scintillation theory be expanded to account for the inhomogeneous ambient atmosphere upon which the turbulence is superimposed. Such coupling between the turbulent and the ambient components of refractivity reduces the scintillation index by less than a factor of two in shallow radio occultations. For stellar occultations the reduction varies between this value for very small projected stellar radii, to approximately a factor of 3.6 when the projected stellar radius above the planetary limb greatly exceeds the radius of the free-space Fresnel zone at this distance. More profound changes are found in the scintillation power spectrum, the shape of which depends strongly on both occultation depth and geometry when coupling to the inhomogeneous background is properly accounted for. Second-order, systematic propagation effects calculated from both geometrical optics and a wave-optical formulation show that the average phase velocity is increased in the presence of turbulence. The finite wavelength dependence of the phase path bias implies that an initially non-dispersive medium becomes slightly dispersive by the addition of turbulence. Atmospheric profiles derived from occultations by turbulent planetary atmospheres differ only slightly from those of the corresponding non-turbulent atmosphere when the weak scattering condition is satisfied.

The tumbling motion of aerodynamically stable bodies entering planetary atmospheres is analyzed considering that the tumbling, its arrest, and the subsequent oscillatory motion are governed by the equation for the fifth Painleve' transcendent. Results based on the asymptotic behavior of the transcendent are applied to study (1) the oscillatory behavior of planetary probe vehicles in relation to aerodynamic heating and loads and (2) the dynamic behavior of the Australian tektites on entering the Earth's atmosphere, under the hypothesis that their origin was the Moon.