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Infrared spectroscopy is an important technique for measuring airborne chemicals, for pollution monitoring and to warn of toxic compound releases. Infrared spectroscopy provides both detection and identification of airborne components. Computer-assisted classification tools, including pattern recognition and artificial neural network techniques, have been applied to a collection of infrared spectra of organophosphorus compounds, and these have successfully discriminated commercial pesticide compounds from military nerve agents, precursors, and hydrolysis products. Infrared spectra for previous tests came from a commercial infrared library, with permission, from military laboratories, and from defense contractors. In order to further test such classification tools, additional infrared spectra from the NIST gas-phase infrared library were added to the data set. These additional spectra probed the tendency of the trained classifiers to misidentify unrelated spectra into the trained classes. Infrared spectra used in this effort were gathered from a variety of sources. Different instrument operators collected them at a number of locations, in a variety of spectral data collection designs, and they were delivered in a variety of digital formats. The spectra were treated mathematically to remove artifacts from their collection. Preprocessing techniques used included Fisher weighting and principal component analysis. Classifications were made using the k-nearest neighbor classifier, feed forward neural networks, trained with a variety of techniques, and radial basis function networks. The results from these classification techniques will be reported and compared.