Probing Sub-nano Level Molecular Packing And Correlated Positron Annihilation Characteristics In Ionic Cross-linked Chitosan Membrane Using Positron Annihilation Spectroscopy - Info and Reading Options

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<div class="hd"> <h1> Probing sub-nano level molecular packing and correlated positron annihilation characteristics in ionic cross-linked Chitosan membrane using Positron Annihilation Spectroscopy </h1> <div class="flex" style="border:0px;padding-bottom:0px;"> </div> <div class="bd" style="border-bottom:1px solid #ced6e0;"> <ul style="margin-top:0px;"> <li> <b> 作者： </b> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Rui%20Xi" style="color:#3060cc;" rel="nofollow"> Rui Xi </a> <sup style="margin-left:0px;"> 1,2 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Xingzhong%20Cao" style="color:#3060cc;" rel="nofollow"> Xingzhong Cao </a> <sup style="margin-left:0px;"> 2 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Meizhen%20Gao" style="color:#3060cc;" rel="nofollow"> Meizhen Gao </a> <sup style="margin-left:0px;"> 1 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Peng%20Zhang" style="color:#3060cc;" rel="nofollow"> Peng Zhang </a> <sup style="margin-left:0px;"> 2 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Minfeng%20Zeng" style="color:#3060cc;" rel="nofollow"> Minfeng Zeng </a> <sup style="margin-left:0px;"> 3 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Baoyi%20Wang" style="color:#3060cc;" rel="nofollow"> Baoyi Wang </a> <sup style="margin-left:0px;"> 2 </sup> <a href="https://chinaxiv.org/user/search.htm?field=author&amp;value=Long%20Wei" style="color:#3060cc;" rel="nofollow"> Long Wei </a> <sup style="margin-left:0px;"> 2 </sup> </li> <li> <b> 作者单位： </b> <div style="margin-left:70px;margin-top:-26px;"> <div> 1. <a href="https://chinaxiv.org/user/search.htm?field=affication&amp;value=Key%20Lab%20for%20Magnetism%20and%20Magnetic%20Materials%20of%20Ministry%20of%20Education,%20School%20of%20Physical%20Science%20and%20Technology,%20Lanzhou%20University,%20Lanzhou%20730000,%20China" style="color:#3060cc;" rel="nofollow"> Key Lab for Magnetism and Magnetic Materials of Ministry of Education, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China </a> </div> <div> 2. <a href="https://chinaxiv.org/user/search.htm?field=affication&amp;value=Institute%20of%20High%20Energy%20Physics,%20Chinese%20Academy%20of%20Sciences,%20Beijing%20100049,%20China" style="color:#3060cc;" rel="nofollow"> Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China </a> </div> <div> 3. <a href="https://chinaxiv.org/user/search.htm?field=affication&amp;value=Zhejiang%20Key%20Laboratory%20of%20Alternative%20Technologies%20for%20Fine%20Chemicals%20Process,%20Shaoxing%20University,%20Shaoxing%20312000,%20China." style="color:#3060cc;" rel="nofollow"> Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, China. </a> </div> </div> </li> <li> <b> 提交时间： </b> 2017-03-26 </li> </ul> </div> <div class="bd" style="margin-top:15px;"> <p style="color:#333;"> <b> 摘要: </b> Chitosan, CS, cross-linked with bivalent palladium has shown enhanced mechanical and thermal properties depending on the transformation of the structure at a microscopic scale. In the present study, CS directly cross-linked by palladium cation membranes (CS-cr-PM) were prepared through solution-casting method. The motion of chitosan chains was great suppressed after crosslinking, making a great reduce of swelling ratio by a water-swelling degree measurement, which led to molecular chain rigidity to be improvement. In order to investigate the chain packing at the molecular level in the ionic cross-linked CS system, the structure of chemically-crosslinked CS is investigated by means of the combined use of wide angle X-ray diffraction (WAXD), Infrared measurements, and a combination of positron annihilation lifetime spectroscopy (PALS) and simultaneous coincidence Doppler broadening (CDB) spectroscopy offers coherent information on both the free-volume related sub-nano level molecular packing and the chemical surrounding of free volume nanoholes in CS-cr-PM as a function of palladium salt loading. The variations in free volume size and size distribution have been determined through the ortho-positroium (o-Ps) lifetime and its lifetime distribution. The studies showed that strong interaction between CS molecules and palladium cations results in the change of crystallinity in formed CS-cr-PM leading to variational chain packing density. Meanwhile, significant inhibition effects on positronium formation due to doping are observed, which could be interpreted in terms of the existence of chlorid ion. Applications of positron annihilation spectroscopy to study the microstructure and correlated positron annihilation characteristics in ionic cross-linked CS system are systematic discussed. </p> <div class="brdge"> <span class="spankwd"> <a href="https://chinaxiv.org/user/search.htm?field=keywords&amp;value=Positron%20annihilation" rel="nofollow"> Positron annihilation </a> </span> </div> <ul> <li> <b> 分类： </b> <a href="https://chinaxiv.org/user/search.htm?field=domain&amp;value=2" rel="nofollow"> 物理学 </a> &gt;&gt; <a href="https://chinaxiv.org/user/search.htm?field=subject&amp;value=44" rel="nofollow"> 凝聚态:结构、力学和热性能 </a> </li> <li> <b> 引用： </b> <a href="https://chinaxiv.org/abs/201703.00581" rel="nofollow"> <font color="#0000FF"> ChinaXiv:201703.00581 </font> </a> (或此版本 <a href="https://chinaxiv.org/abs/201703.00581v1" rel="nofollow"> <font color="#0000FF"> ChinaXiv:201703.00581V1 </font> </a> ) <br /> <a style="margin-left:45px;" rel="nofollow"> doi:10.12074/201703.00581 </a> <br /> <a href="https://www.cstr.cn/CSTR:32003.36.ChinaXiv.201703.00581.V1" style="margin-left:45px;" rel="nofollow"> <font color="#0000FF"> CSTR:32003.36.ChinaXiv.201703.00581.V1 </font> </a> </li> <li> <b> 推荐引用方式： </b> <span> Rui Xi,Xingzhong Cao,Meizhen Gao,Peng Zhang,Minfeng Zeng,Baoyi Wang,Long Wei.(2017).Probing sub-nano level molecular packing and correlated positron annihilation characteristics in ionic cross-linked Chitosan membrane using Positron Annihilation Spectroscopy.中国科学院科技论文预发布平台.[ChinaXiv:201703.00581] </span> </li> </ul> </div> <div class="ft"> <h4> <span> 版本历史 </span> </h4> <table> <tr> <td> <b> [V1] </b> </td> <td> 2017-03-26 19:36:59 </td> <td> ChinaXiv:201703.00581V1 </td> <td> <a class="btn" href="https://chinaxiv.org/user/download.htm?id=6815" rel="nofollow"> 下载全文 </a> </td> </tr> </table> </div> </div>

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