Emulsification and polymerization of alkyd resins - Info and Reading Options

"Emulsification and polymerization of alkyd resins" Table Of Contents:

• 1- Machine generated contents note: I
• 2- I
• 3- 1. ALKYD RESINS, VEGETABLE OILS AND AUTOXIDATIVE
• 4- POLYMERIZATION
• 5- 1.1. Goals of Research and Development in Alkyd Emulsions
• 6- 1.2. Historical Background of Alkyds, Oils and Emulsions
• 7- 1.2.1. Vegetable Oils and Resins
• 8- 1.2.2. Autoxidative Polymerization of Vegetable Oils and
• 9- Resins
• 10- 1.2.3. Emulsified Oils and Resins
• 11- 1.3. Theoretical Considerations
• 12- 1.3.1. Intrinsic Viscosity
• 13- 1.3.2. Hydrophile-Lipophile Balance (HLB)
• 14- 1.3.3. Diffusion of Oxygen in an Emulsion
• 15- 1.3.4. Solubility of Air and Oxygen in Aqueous Phase
• 16- 1.3.5. Swelling Ratio
• 17- 1.4. Justification for Research and Development
• 18- 2. SYNTHESIS AND POLYMERIZATION OF ALKYDS
• 19- 2.1. Alkyd Synthesis Procedure
• 20- 2.2. Emulsification Procedure
• 21- 2.3. Autoxidation Procedure
• 22- 2.4. Materials
• 23- 2.5. Characterization
• 24- 2.5.1. Emulsion Particle Size
• 25- 2.5.2. Emulsion Characterization
• 26- 2.5.3. Film Characterization
• 27- 2.5.4. Intrinsic Viscosity Measurement
• 28- 2.5.5. Swell Ratio
• 29- 2.5.6. Turbidimetric Measurement of Swelling Ratio
• 30- 2.5.7. Dissolved Oxygen in Aqueous Phase
• 31- 3. EMULSION AND KINETIC STUDIES OF AUTOXIDATIVE
• 32- POLYMERIZATION
• 33- 3.1. Emulsifier Studies
• 34- 3.1.1. Emulsifier Sources and Chemical Structures
• 35- 3.1.2. Emulsifiers and Emulsion Stability
• 36- 3.1.3. Emulsifiers and Freeze-Thaw Stability
• 37- 3.1.4. Emulsifiers and Film Characterization
• 38- xiii
• 39- 3.2. Phase Ratio and Co-Solvent Study
• 40- 3.2.1. Solvent Alkyd Emulsions
• 41- 3.2.2. Co-Solvent Containing Emulsions
• 42- 3.3. Studies on the Autoxidative Crosslinking of Emulsified
• 43- Soya Oil
• 44- 3.3.1. Autoxidation Reaction of Emulsified Soya Oil
• 45- 3.3.2. Catalysis of Autoxidation Reaction of Soya Oil
• 46- 3.4. Studies of the Autoxidative Crosslinking of Emulsified
• 47- Alkyd Particles
• 48- 3.4.1. Autoxidation Reaction of Emulsified Alkyd Resins
• 49- 3.4.2. Non-catalyzed Autoxidation Reaction
• 50- 3.4.3. Benzoyl Peroxide Catalysis in the Alkyd Phase
• 51- 3.4.4. Cobalt Naphthenate Catalysis in Aqueous Phase
• 52- 3.4.5. Autoxidized Emulsion Characterization
• 53- 3.4.6. Post pH-Adjustment of Autoxidized Emulsion
• 54- 3.4.7. pH Adjustment Prior to the Autoxidation
• 55- 3.4.8. Cobalt Naphthenate Catalysis in Alkyd Phase
• 56- 3.4.9. Post-Addition of Emulsifier
• 57- 3.4.10. pH Effect on Reaction Rate
• 58- 3.4.11. Increased Oxygen Concentration and Catalysis
• 59- 3.4.12. Scanning Electron Microscopy
• 60- 3.4.13. Water Clean-Up of Emulsion
• 61- 3.4.14. Comparison to Alkyd-Solvent System
• 62- 3.4.15. Effect of Emulsifier Structure on Reaction Rate
• 63- 3.5. Kinetic Study
• 64- 3.5.1. Oxygen Concentration Relationship
• 65- 3.5.2. Correlation of Swell Ratio and Percent Transmittance
• 66- 3.5.3. Catalysis Effect
• 67- 3.5.4. Temperature Effect
• 68- 3.5.5. Agitation Rate Effect
• 69- 3.5.6. Molecular Weight Effect
• 70- 3.6. Studies on Emulsion Particle Size
• 71- 3.6.1. Particle Size with Reaction Time
• 72- 3.6.2. Average Particle Size with Homogenization
• 73- 3.6.3. Particle Size after One Year of Shelf Life
• 74- 3.7. Alkyd Oil Length and Conjugation Study
• 75- 3.7.1. Alkyd Oil Length Study
• 76- 3.7.2. Alkyd Conjugation Study
• 77- 4. EXPERIMENTAL RESULTS, RESEARCH
• 78- AND COMMERCIALIZATION OF TECHNOLOGY
• 79- 4.1. Autoxidative Crosslinking of Vegetable Oil
• 80- 4.2. Autoxidative Crosslinking of Vegetable Oil Alkyds
• 81- 4.3. Emulsification
• 82- 4.4. Continuing Research and Developments
• 83- 4.5. Commercialization of Alkyd Emulsions
• 84- APPENDIX - FIGURES
• 85- APPENDIX - TABLES
• 86- REFERENCES
• 87- INDEX.

Read “Emulsification and polymerization of alkyd resins”:

Read “Emulsification and polymerization of alkyd resins” by choosing from the options below.