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This is a continuation of our papers \cite{AP2} and \cite{AP3}. In those papers we obtained estimates for finite differences $(\D_Kf)(A)=f(A+K)-f(A)$ of the order 1 and $(\D_K^mf)(A)\df\sum\limits_{j=0}^m(-1)^{m-j}(m\j)f\big(A+jK\big)$ of the order $m$ for certain classes of functions $f$, where $A$ and $K$ are bounded self-adjoint operator. In this paper we extend results of \cite{AP2} and \cite{AP3} to the case of unbounded self-adjoint operators $A$. Moreover, we obtain operator Bernstein type inequalities for entire functions of exponential type. This allows us to obtain alternative proofs of the main results of \cite{AP2}. We also obtain operator Bernstein type inequalities for functions of unitary operators. Some results of this paper as well as of the papers \cite{AP2} and \cite{AP3} were announced in \cite{AP1}.

We introduce a generalized index for certain meromorphic, unbounded, operator-valued functions. The class of functions is chosen such that energy parameter dependent Dirichlet-to-Neumann maps associated to uniformly elliptic partial differential operators, particularly, non-self-adjoint Schr\"odinger operators, on bounded Lipschitz domains, and abstract operator-valued Weyl-Titchmarsh $M$-functions and Donoghue-type $M$-functions corresponding to closed extensions of symmetric operators belong to it. The principal purpose of this paper is to prove index formulas that relate the difference of the algebraic multiplicities of the discrete eigenvalues of Robin realizations of non-self-adjoint Schr\"{o}dinger operators, and more abstract pairs of closed operators in Hilbert spaces with the generalized index of the corresponding energy dependent Dirichlet-to-Neumann maps and abstract Weyl-Titchmarsh $M$-functions, respectively.

In this paper we present equivalence results for several types of unbounded operator functions. A generalization of the concept equivalence after extension is introduced and used to prove equivalence and linearization for classes of unbounded operator functions. Further, we deduce methods of finding equivalences to operator matrix functions that utilizes equivalences of the entries. Finally, a method of finding equivalences and linearizations to a general case of operator matrix polynomials is presented.