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This report presents the results of w-band complex permittivity measurements performed in NASA Langley's Electromagnetics Research Branch. The test articles included in the permittivity study were flat panels of materials which are under consideration for use in a radome for the Passive Millimeter Wave Camera (PMMWC) flight experiment. This experiment is scheduled to fly on the Air Force's 'Speckled Trout' aircraft in late 1997. The radome design is very important because the PMMWC can tolerate only a small amount of electromagnetic loss through the radome. A free space measurement system was used to obtain complex reflection and transmission coefficients of the samples. The frequency of interest was 89 GHz, so measurements were performed over a range of 79 to 99 GHz. The transmission and reflection coefficients were used, along with the measured sample thickness, to calculate complex permittivity over the frequency range. The material samples measured in this study can be divided into four categories: skin materials, core materials, coating materials, and layered samples.