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Macrocyclic Polyamines by Xiaoqin Yu
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1DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines
By Defense Technical Information Center
Poly(vinyl)acetate and poly(methyl methacrylate) with controlled molecular weights and narrow polydispersities (1.55-1.68) were prepared by radical polymerization using initiators based on redox systems: benzoyl peroxide and Cr(OAC)2 complexed by macrocyclic polyamines, in THF, at ambient temperatures. Structure of N-based ligands affects the initiation rate and propagation control. The highest degree of control was achieved by using chromium atom complexed by 1,4,7,10,13,16-hexaazacyclooctadecane trisulfate.
“DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines” Metadata:
- Title: ➤ DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines
- Author: ➤ Defense Technical Information Center
- Language: English
“DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines” Subjects and Themes:
- Subjects: ➤ DTIC Archive - Mardare, Daniela - CARNEGIE-MELLON UNIV PITTSBURGH PA DEPT OF CHEMISTRY - *METHYL RADICALS - *POLYMERIZATION - *ORGANOMETALLIC COMPOUNDS - *AMINES - *CHROMIUM - *VINYL RADICALS - *CHEMICAL RADICALS - *ACETATES - *METHACRYLATES - CONTROL - PROPAGATION - STRUCTURES - PEROXIDES - CLEAVAGE - OXIDATION REDUCTION REACTIONS - FREE RADICALS - LIGANDS - REVERSIBLE - ATOMS - RATES - MOLECULAR WEIGHT - TEMPERATURE - COMPLEX COMPOUNDS
Edition Identifiers:
- Internet Archive ID: DTIC_ADA280828
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The book is available for download in "texts" format, the size of the file-s is: 3.92 Mbs, the file-s for this book were downloaded 59 times, the file-s went public at Sun Mar 18 2018.
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2DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.
By Defense Technical Information Center
Five new macrocyclic polyamine fluorophores containing two dansylamidoethyl side arms (3a-3e) have been prepared. As shown in Scheme 1, the appropriate macrocyclic polyamine (la-le) was treated with N-dansylaziridine in acetonitrile to form 3a-3e. The yields of the new fluorophores are given in the scheme.
“DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.” Metadata:
- Title: ➤ DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.
- Author: ➤ Defense Technical Information Center
- Language: English
“DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.” Subjects and Themes:
- Subjects: ➤ DTIC Archive - Xue, G. P. - BRIGHAM YOUNG UNIV PROVO UT DEPT OF CHEMISTRY AND BIOCHEMISTRY - *FLUORESCENCE - *POLYMERS - *AMINO ACIDS - *METHYLAL - ACETONITRILE - SIDES - ETHYLENES.
Edition Identifiers:
- Internet Archive ID: DTIC_ADA368666
Downloads Information:
The book is available for download in "texts" format, the size of the file-s is: 2.75 Mbs, the file-s for this book were downloaded 67 times, the file-s went public at Wed Apr 25 2018.
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