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Macrocyclic Polyamines by Xiaoqin Yu

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1DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines

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Poly(vinyl)acetate and poly(methyl methacrylate) with controlled molecular weights and narrow polydispersities (1.55-1.68) were prepared by radical polymerization using initiators based on redox systems: benzoyl peroxide and Cr(OAC)2 complexed by macrocyclic polyamines, in THF, at ambient temperatures. Structure of N-based ligands affects the initiation rate and propagation control. The highest degree of control was achieved by using chromium atom complexed by 1,4,7,10,13,16-hexaazacyclooctadecane trisulfate.

“DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines” Metadata:

  • Title: ➤  DTIC ADA280828: Radical Polymerization Of Vinyl Acetate And Methyl Methacrylate Using Organochromium Initiators Complexed With Macrocyclic Polyamines
  • Author: ➤  
  • Language: English

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The book is available for download in "texts" format, the size of the file-s is: 3.92 Mbs, the file-s for this book were downloaded 59 times, the file-s went public at Sun Mar 18 2018.

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2DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.

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Five new macrocyclic polyamine fluorophores containing two dansylamidoethyl side arms (3a-3e) have been prepared. As shown in Scheme 1, the appropriate macrocyclic polyamine (la-le) was treated with N-dansylaziridine in acetonitrile to form 3a-3e. The yields of the new fluorophores are given in the scheme.

“DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.” Metadata:

  • Title: ➤  DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.
  • Author: ➤  
  • Language: English

“DTIC ADA368666: New Macrocyclic Polyamines Containing Two Dansylamidoethyl Side Arms.” Subjects and Themes:

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The book is available for download in "texts" format, the size of the file-s is: 2.75 Mbs, the file-s for this book were downloaded 67 times, the file-s went public at Wed Apr 25 2018.

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