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1The Measurement Of Ionic Velocities In Aqueous Solution, And The Existence Of Complex Ions.

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2Highly Charged Ions In A Dilute Plasma: An Exact Asymptotic Solution Involving Strong Coupling

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The ion sphere model introduced long ago by Salpeter is placed in a rigorous theoretical setting. The leading corrections to this model for very highly charged but dilute ions in thermal equilibrium with a weakly coupled, one-component background plasma are explicitly computed, and the subleading corrections shown to be negligibly small. This is done using effective field theory methods advocated by Brown and Yaffe. Thus, corrections to nuclear reaction rates that such highly charged ions may undergo can be computed precisely. Moreover, their contribution to the equation of state can also be computed with precision. Such analytic results for very strong coupling are rarely available, and they can serve as benchmarks for testing computer models in this limit.

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3DTIC ADA142335: The Transfer Of Atoms, Ions And Molecular Groups In Solution. Part 3. Monte Carlo Methods For The Evaluation Of Rate Constants.

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This paper contains a report of investigations into the application of the transition state theory to atom, ion and molecular group transfers. Attention is concentrated on the formulation of Monte Carlo methods of simulation. It is found possible to derive forms for the rate constant in the diabatic and adiabatic limits which immediately suggest the manner in which Monte Carlo averages should be carried out. The method is illustrated by considering the reactive inversion of a bent A-B-A molecule in a two-dimensional system of disk-like solvent. The activation energy is determined for the transformation to a linear transition state, and a tally is kept of the average adiabaticity of the reaction. These results indicate that the extention of the method to more realistic systems ought to yield valuable information about the mechanisms of reactions in condensed phases.

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4IONS IN SOLUTION

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This paper contains a report of investigations into the application of the transition state theory to atom, ion and molecular group transfers. Attention is concentrated on the formulation of Monte Carlo methods of simulation. It is found possible to derive forms for the rate constant in the diabatic and adiabatic limits which immediately suggest the manner in which Monte Carlo averages should be carried out. The method is illustrated by considering the reactive inversion of a bent A-B-A molecule in a two-dimensional system of disk-like solvent. The activation energy is determined for the transformation to a linear transition state, and a tally is kept of the average adiabaticity of the reaction. These results indicate that the extention of the method to more realistic systems ought to yield valuable information about the mechanisms of reactions in condensed phases.

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5The Influence Of The Metallic Ions In An Electrolytic Solution Upon The Electric Potential Of A Metal Placed In The Solution

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Thesis (Ph.D.) - Leland Stanford Junior University, 1916

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6Ions In Solution: Density Corrected Density Functional Theory (DC-DFT)

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Standard density functional approximations often give questionable results for odd-electron radical complexes, with the error typically attributed to self-interaction. In density corrected density functional theory (DC-DFT), certain classes of density functional theory calculations are significantly improved by using densities more accurate than the self-consistent densities. We discuss how to identify such cases, and how DC-DFT applies more generally. To illustrate, we calculate potential energy surfaces of HO$\cdot$Cl$^-$ and HO$\cdot$H$_2$O complexes using various common approximate functionals, with and without this density correction. Commonly used approximations yield wrongly shaped surfaces and/or incorrect minima when calculated self consistently, while yielding almost identical shapes and minima when density corrected. This improvement is retained even in the presence of implicit solvent.

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7Selected Specific Rates Of Reactions Of Transients From Water In Aqueous Solution. III. Hydroxyl Radical And Perhydroxyl Radical And Their Radical Ions

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Standard density functional approximations often give questionable results for odd-electron radical complexes, with the error typically attributed to self-interaction. In density corrected density functional theory (DC-DFT), certain classes of density functional theory calculations are significantly improved by using densities more accurate than the self-consistent densities. We discuss how to identify such cases, and how DC-DFT applies more generally. To illustrate, we calculate potential energy surfaces of HO$\cdot$Cl$^-$ and HO$\cdot$H$_2$O complexes using various common approximate functionals, with and without this density correction. Commonly used approximations yield wrongly shaped surfaces and/or incorrect minima when calculated self consistently, while yielding almost identical shapes and minima when density corrected. This improvement is retained even in the presence of implicit solvent.

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8Electron Transfer Reactions Of Complex Ions In Solution

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viii,103p. : 21 cm

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9Ions In Aqueous Systems; An Introduction To Chemical Equilibrium And Solution Chemistry

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viii,103p. : 21 cm

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10Ions In Solution (3) : Inorganic Properties

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viii,103p. : 21 cm

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11DTIC ADA1024270: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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12DTIC ADA1024272: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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13Electron Transfer Reactions Of Complex Ions In Solution. --

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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14Ion Exchange Sorption Study Of Some Metal Ions And Organic Ligands In Solution

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Book Source: Digital Library of India Item 2015.13904 dc.contributor.author: Kirti Khare dc.date.accessioned: 2015-06-23T22:35:42Z dc.date.available: 2015-06-23T22:35:42Z dc.identifier.barcode: 5010010155048 dc.identifier.origpath: /data1/upload/0009/805 dc.identifier.copyno: 1 dc.identifier.uri: http://www.new.dli.ernet.in/handle/2015/13904 dc.description.scanningcentre: IIIT, Allahabad dc.description.main: 1 dc.description.tagged: 0 dc.description.totalpages: 244 dc.format.mimetype: application/pdf dc.language.iso: English dc.publisher.digitalrepublisher: IIIT, Allahabad dc.publisher: Allahabad University dc.rights: Out_of_copyright dc.source.library: Allahabad University dc.subject.classification: Philosophy dc.title: Ion Exchange Sorption Study Of Some Metal Ions And Organic Ligands In Solution

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15Metal Ions In Aqueous Solution

Book Source: Digital Library of India Item 2015.13904 dc.contributor.author: Kirti Khare dc.date.accessioned: 2015-06-23T22:35:42Z dc.date.available: 2015-06-23T22:35:42Z dc.identifier.barcode: 5010010155048 dc.identifier.origpath: /data1/upload/0009/805 dc.identifier.copyno: 1 dc.identifier.uri: http://www.new.dli.ernet.in/handle/2015/13904 dc.description.scanningcentre: IIIT, Allahabad dc.description.main: 1 dc.description.tagged: 0 dc.description.totalpages: 244 dc.format.mimetype: application/pdf dc.language.iso: English dc.publisher.digitalrepublisher: IIIT, Allahabad dc.publisher: Allahabad University dc.rights: Out_of_copyright dc.source.library: Allahabad University dc.subject.classification: Philosophy dc.title: Ion Exchange Sorption Study Of Some Metal Ions And Organic Ligands In Solution

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16Solution Reaction Design: Electroaccepting And Electrodonating Powers Of Ions In Solution.

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This article is from Nanoscale Research Letters , volume 7 . Abstract By considering a first-order variation in electroaccepting and electrodonating powers, ω±, induced by a change from gas to aqueous solution phase, the solvent effect on ω± for charged ions is examined. The expression of electroaccepting and electrodonating powers in the solution phase, ω±s, is obtained through establishing the quantitative relationship between the change of the ω± due to the solvation and the hydration free energy. It is shown that cations are poorer electron acceptors and anions are poorer electron donors in solution compared to those in gas phase. We have proven that the scaled aqueous electroaccepting power, ω+s, of cations can act as a good descriptor of the reduction reaction, which is expected to be applied in the design of solution reactions.

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17DTIC ADA142334: The Transfer Of Atoms, Ions And Molecular Groups In Solution. Part 2. Tunnelling Between Harmonic Wells,

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The use of a harmonic-oscillator model is considered to investigate the tunneling of atoms, ions and molecular groups between positions of equilibrium for systems in condensed phases. The use of the oscillator model is warranted in many instances for which one has reasonably accurate information about the vibrational frequencies of atoms or molecular groups together with information about the distance over which the species transfers. Thus, the harmonic-oscillator model can be used in the absence of more complete information to make estimates of the rates of various kinds of heavy-centre transfers in solution. In this paper we present a general treatment for the determination of the tunnel factors which are involved in the transfer.

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18The Osmotic Pressure Of The Ions And Of The Undissociated Molecules Of Salts In Aqueous Solution

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"The Osmotic Pressure of the Ions and of the Undissociated Molecules of Salts in Aqueous Solution" is an article from Proceedings of the National Academy of Sciences of the United States of America, Volume 1 . View more articles from Proceedings of the National Academy of Sciences of the United States of America . View this article on JSTOR . View this article's JSTOR metadata . You may also retrieve all of this items metadata in JSON at the following URL: https://archive.org/metadata/jstor-83380

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19The Measurement Of Ionic Velocities In Aqueous Solution, And The Existence Of Complex Ions.

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The Measurement of Ionic Velocities in Aqueous Solution, and the Existence of Complex Ions. Steele, B Proceedings of the Royal Society of London (1854-1905). 1901-01-01. 68:358–360

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20The Measurement Of Ionic Velocities In Aqueous Solution, And The Existence Of Complex Ions

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The Measurement of Ionic Velocities in Aqueous Solution, and the Existence of Complex Ions. Steele, B Philosophical Transactions of the Royal Society of London. Series A, Containing Papers of a Math. or Phys. Character (1896-1934). 1902-01-01. 198:105–145

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21DTIC ADA102427: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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22DTIC ADA1024271: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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23DTIC ADA1024278: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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24Ions In Solution

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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25DTIC ADA1024274: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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26Metal Ions In Aqueous Solution

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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27DTIC ADA142333: The Transfer Of Atoms, Ions And Molecular Groups In Solution. Part 1. Models And Limits,

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The theory of the activated complex, as formulated by Marcus, is applied to the transfer in condensed phases of atoms, ions and molecular groups. Particular attention is given to reactions which take place in the diabatic limit. A Born-Oppenheimer-Holstein separation is developed in order to separate the degrees of freedom of the reactive subsystem from those of the environment; perturbations which can drive the reaction in the diabatic limit are identified. An analysis of a simple system is carried out. The system is two-dimensional and consists of a lithium cation which migrates (via activation) from one site of solvation to another.

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28Qualitative Analysis And The Properties Of Ions In Aqueous Solution

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x, 196 p. 25 cm

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29Metal Ions In Solution

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x, 196 p. 25 cm

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30Nuclear Magnetic Resonance Study Of Hydrogen Bihalide Ions In Solution

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x, 196 p. 25 cm

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31DTIC ADA1024273: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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32DTIC ADA1024276: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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33Qualitative Analysis And The Properties Of Ions In Aqueous Solution

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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34DTIC ADA1024275: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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35The Kinetics Of The Oxidation Of Iodine By Dichromate Ions In Acid Solution

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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36DTIC ADA1024277: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

By

Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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37Ions In Solution

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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38The Kinetics Of The Oxidatioin Of Iodine By Dichromate Ions In Acid Solution

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A study of the kinetics of the oxidation of iodine to iodate ion by dichromate ions in acid aqueous solution was undertaken.

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39The Periodic Table And Chemical Bonding; [and, Ions In Solution]

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68,47p. : 30cm

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40Ions In Solution

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Book Source: Digital Library of India Item 2015.205711 dc.contributor.author: Gurney. R.w dc.date.accessioned: 2015-07-09T14:15:31Z dc.date.available: 2015-07-09T14:15:31Z dc.date.digitalpublicationdate: 2005-02-23 dc.date.citation: 1936 dc.identifier.barcode: 1040010074884 dc.identifier.origpath: /data_copy/upload/0074/889 dc.identifier.copyno: 1 dc.identifier.uri: http://www.new.dli.ernet.in/handle/2015/205711 dc.description.scannerno: 5 dc.description.scanningcentre: IISc, Bangalore dc.description.main: 1 dc.description.tagged: 0 dc.description.totalpages: 214 dc.format.mimetype: application/pdf dc.language.iso: English dc.publisher.digitalrepublisher: Svinfo dc.publisher: Cambridge At The University Press dc.rights: Out_of_copyright dc.source.library: Jrd Tata Memorial Library,indian Institute Of Science,bangalore dc.subject.classification: Natural Sciences dc.subject.classification: Chemistry.crystallogrpahy.mineralogy dc.subject.classification: Practical Laboratory Chemistry.preparative And Experimental Chemistry dc.subject.keywords: Atomic Ions dc.subject.keywords: Solvent Molecules dc.title: Ions In Solution

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41Highly Charged Ions In A Weakly Coupled Plasma: An Exact Solution

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The ion sphere model introduced long ago by Salpeter is placed in a rigorous theoretical setting. The leading corrections to this model for very highly charged but dilute ions in thermal equilibrium with a weakly coupled, one-component background plasma are explicitly computed, and the subleading corrections are shown to be negligibly small. Such analytic results for very strong coupling are rarely available, and they can serve as benchmarks for testing computer models in this limit.

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42DTIC ADA1024279: Photoelectron Emission Spectroscopy Of Weak Acids And Bases And Their Ions In Aqueous Solution.

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Threshold energies E sub t are determined for 14 weak acids and three bases and their ions. Values of E sub t are interpreted in terms of dissociation or protonation reactions involving species produced by photoionization. Electron transfer to weak acid molecules in solution is shown to occur for emission by inorganic anions and cations and weak acids. (Author)

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43Considerations On Organic Compounds In Solution And Inorganic Ions In Glasses As Fluorescent Standard Reference Materials

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Journal of Research of the National Bureau of Standards

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44Ions In Solution And Their Solvation

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Journal of Research of the National Bureau of Standards

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45The Kinetics Of The Oxidatioin Of Iodine By Dichromate Ions In Acid Solution

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A study of the kinetics of the oxidation of iodine to iodate ion by dichromate ions in acid aqueous solution was undertaken.

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46DTIC AD0480925: THE KINETICS OF THE OXIDATION OF IODINE BY DICHROMATE IONS IN ACID SOLUTION

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A study of the kinetics of the oxidation of I2 to iodate ion by dichromate ions in acid aqueous solution was undertaken. Ionic strength and temperature were maintained constant and the progress of the reaction was followed by spectrophotometric analysis of unreacted I2 extracted into CCl4. It was established that the reaction was 1/2 order in I2, but no exact relationship was found with hydrogen ion or any hexavalent Cr species. First order dependency on acid and H2CrO4 was found to be a possibility, or at least useful approximation, although a more precise knowledge of all Cr(VI) equilibria relations at high ionic strengths than is available would be needed for verification. A multi-step rate determining mechanism is possible, although low I2 solubility coupled with high required concentrations of other constituents limit available techniques and would probably, in this event, make determination of the complete rate expression difficult.

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47Metal Ions In Solution

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A study of the kinetics of the oxidation of I2 to iodate ion by dichromate ions in acid aqueous solution was undertaken. Ionic strength and temperature were maintained constant and the progress of the reaction was followed by spectrophotometric analysis of unreacted I2 extracted into CCl4. It was established that the reaction was 1/2 order in I2, but no exact relationship was found with hydrogen ion or any hexavalent Cr species. First order dependency on acid and H2CrO4 was found to be a possibility, or at least useful approximation, although a more precise knowledge of all Cr(VI) equilibria relations at high ionic strengths than is available would be needed for verification. A multi-step rate determining mechanism is possible, although low I2 solubility coupled with high required concentrations of other constituents limit available techniques and would probably, in this event, make determination of the complete rate expression difficult.

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48Fourier Transform Infrared, X-Ray Diffraction And Energy Dispersive X-Ray Analysis Studies On The Adsorption Of Copper Ii Ions Prepared From Mimusops Elengi Leaves In Aqueous Solution Against Acid Activated Carbon

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Adsorption considers were finished by watching the effects of various preliminary limits ejection of copper (II) particles from watery course of action. Morphology of adsorbent on account of adsorption has been destitute down PH, FT-IR spectra, EDX and XRD examination. The data were fitted into the Langmuir and Freundlich adsorption isotherm conditions. Thermodynamics limits like change in free imperativeness, enthalpy and entropy were resolved.

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49Adsorption Of Pb2+ Ions In Aqueous Solution By Activated Carbon

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This study presents the synthesis of activated carbon material by simple thermal treatment of bamboo wood. The synthetic AC shows an amorphous and porous structure. The adsorption of lead ions on synthetic AC was effectuated. The obtained results show that the synthetic AC has a high ability for lead ions removal with high efficiency of 97% after 2 hours of adsorption experiment. The isotherm study showed that lead removal is suitable for both the Langmuir and Freundlich models with a high value of correlation coefficient (R 2 = 0.97). The maximum capacity of lead ions removal is high (Q m = 24570 mg/g). Summing up , AC material synthesized from bamboo wood presents a potential material for lead ions removal from the aqueous solution.

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Source: The Open Library

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1IONS IN SOLUTION

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  • Title: IONS IN SOLUTION
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  • Language: English
  • Number of Pages: Median: 220
  • Publisher: ➤  DOVER PUBLICATIONS, INC. - Franklin Classics
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  • First Year Published: 1962
  • Is Full Text Available: Yes
  • Is The Book Public: Yes
  • Access Status: Public

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    Source: LibriVox

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    1Oh, For a Home of Rest!

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    Eliza Paul Kirkbride Gurney was a Quaker minister who, when her husband Joseph John Gurney died in 1847, continued the labours of a traveling minister. She corresponded with Abraham Lincoln, who was found to have a two year old letter from Eliza, carefully “treasured up” by him in his breast pocket when assassinated. - Summary by David Lawrence

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    • Number of Sections: 15
    • Total Time: 00:25:14

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    2Severn and Somme

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    The English poet Ivor Gurney wrote these poems while serving in the First World War. In them he contrasts the wartime desolation of the area around the River Somme in northern France with the natural beauty of the valley of the River Severn in his native Gloucestershire. - Summary by Alan Mapstone

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    • Format: Audio
    • Number of Sections: 45
    • Total Time: 01:03:49

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    3War's Embers

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    A collection of poems by the Gloucestershire-born English poet Ivor Gurney describing his feelings about the First World War, during which he served on the Western Front and was wounded by a mustard gas attack, and its aftermath. - Summary by Alan Mapstone

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    • Number of Sections: 58
    • Total Time: 01:37:21

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