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We use the Newns-Anderson Hamiltonian to describe many-body electronic processes that occur when hyperthermal alkali atoms scatter off metallic surfaces. Following Brako and Newns, we expand the electronic many-body wavefunction in the number of particle-hole pairs (we keep terms up to and including a single particle-hole pair). We extend their earlier work by including level crossings, excited neutrals and negative ions. The full set of equations of motion are integrated numerically, without further approximations, to obtain the many-body amplitudes as a function of time. The velocity and work-function dependence of final state quantities such as the distribution of ion charges and excited atomic occupancies are compared with experiment. In particular, experiments that scatter alkali ions off clean Cu(001) surfaces in the energy range 5 to 1600 eV constrain the theory quantitatively. The neutralization probability of Na$^+$ ions shows a minimum at intermediate velocity in agreement with the theory. This behavior contrasts with that of K$^+$, which shows ... (7 figures, not included. Figure requests: [email protected])

We use the Newns-Anderson Hamiltonian to describe many-body electronic processes that occur when hyperthermal alkali atoms scatter off metallic surfaces. Following Brako and Newns, we expand the electronic many-body wavefunction in the number of particle-hole pairs (we keep terms up to and including a single particle-hole pair). We extend their earlier work by including level crossings, excited neutrals and negative ions. The full set of equations of motion are integrated numerically, without further approximations, to obtain the many-body amplitudes as a function of time. The velocity and work-function dependence of final state quantities such as the distribution of ion charges and excited atomic occupancies are compared with experiment. In particular, experiments that scatter alkali ions off clean Cu(001) surfaces in the energy range 5 to 1600 eV constrain the theory quantitatively. The neutralization probability of Na$^+$ ions shows a minimum at intermediate velocity in agreement with the theory. This behavior contrasts with that of K$^+$, which shows ... (7 figures, not included. Figure requests: [email protected])

A Feshbach resonance in the s-wave scattering length occurs if the energy of the two atoms in the incoming open channel is close to the energy of a bound state in a coupled closed channel. Starting from the microscopic hamiltonian that describes this situation, we derive the effective atom-molecule theory for a Bose gas near a Feshbach resonance. In order to take into account all two-body processes, we have to dress the bare couplings of the atom-molecule model with ladder diagrams. This results in a quantum field theory that exactly reproduces the scattering amplitude of the atoms and the bound-state energy of the molecules. Since these properties are incorporated at the quantum level, the theory can be applied both above and below the critical temperature of the gas. Moreover, making use of the true interatomic potentials ensures that no divergences are encountered at any stage of the calculation. We also present the mean-field theory for the Bose-Einstein condensed phase of the gas.

Manipulating expressions in many-body perturbation theory becomes unwieldily with increasing order of the perturbation theory. Here I derive a set of theorems for efficient simplification of such expressions. The derived rules are specifically designed for implementing with symbolic algebra tools. As an illustration, we count the numbers of Brueckner-Goldstone diagrams in the first several orders of many-body perturbation theory for matrix elements between two states of a mono-valent system.

Manipulating expressions in many-body perturbation theory becomes unwieldily with increasing order of the perturbation theory. Here I derive a set of theorems for efficient simplification of such expressions. The derived rules are specifically designed for implementing with symbolic algebra tools. As an illustration, we count the numbers of Brueckner-Goldstone diagrams in the first several orders of many-body perturbation theory for matrix elements between two states of a mono-valent system.

Manipulating expressions in many-body perturbation theory becomes unwieldily with increasing order of the perturbation theory. Here I derive a set of theorems for efficient simplification of such expressions. The derived rules are specifically designed for implementing with symbolic algebra tools. As an illustration, we count the numbers of Brueckner-Goldstone diagrams in the first several orders of many-body perturbation theory for matrix elements between two states of a mono-valent system.

An algorithm, based on numerical description of the terms of many-body perturbation theory (Goldstone diagrams), is presented. The algorithm allows the use of the same piece of computer code to evaluate any particular diagram in any specific order of the perturbation theory or to calculate similar terms in other areas of the many-body theory, like e.g. terms in the coupled-cluster equations. The use of the algorithm is illustrated by calculating the second and third order correlation corrections to the removal energies of electrons from the ground state of sodium, copper and gallium and by calculating the hyperfine structure constants of sodium in the linearized single-double coupled cluster approximation.

An algorithm, based on numerical description of the terms of many-body perturbation theory (Goldstone diagrams), is presented. The algorithm allows the use of the same piece of computer code to evaluate any particular diagram in any specific order of the perturbation theory or to calculate similar terms in other areas of the many-body theory, like e.g. terms in the coupled-cluster equations. The use of the algorithm is illustrated by calculating the second and third order correlation corrections to the removal energies of electrons from the ground state of sodium, copper and gallium and by calculating the hyperfine structure constants of sodium in the linearized single-double coupled cluster approximation.